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The Optical Limier Behavior and nonlinear optical properties of Nano composite Embedded in Polymer Films Prepared by PLD Technique

Hanan Alkhazaali

  

 The multilayers thin films of (TiO2/ZnO/CdS) prepared by using pulsed laser deposition technique (PLD) under vacuum of 10-5 mbar using pulsed Nd:YAG laser with (1064 nm), which deposited on a glass and silicon wafer substrates Poly Methyl Methacylate with chemical form (C5O2H8) was dissolved in (8mL) chloroform solvent

,and doped with nanoparticles of (TiO2/ZnO/CdS) with (25%) doped of energy (800mJ) with number of pulses (1000), X–ray diffraction measurements for sam­ple showed that has polycrystalline structures, cubic & orthorhombic CdS structure, tetragonal & monoclinic TiO2 structure, hexagonal ZnO structure, AFM images show contrast in homogeneity of grains’ surface of films graded various region, and there is gradient in color, The optical properties of all thin films are investigated from absorption spectrum in the UV-VIS through the range of (300-900) nm. The results show that the best optical absorbance edge is in (527.65 nm), also the optical con­stants such as: extinction coefficient and refractive index for all prepared thin films are calculated, the purpose of the study was to obtain the nonlinearly refraction and absorption coefficient of (TiO2/ZnO/CdS). The results close aperture Z-scan self-focusing effect while the open aperture Z-scan of the sample show a two photon absorp­tion (TPA). Result optical limiting is quite encouraging for possible applications in nonlinear optical devices.